Studies on 3H-Indole. II. Rearrangement of Acyl Chloride Adducts. (1)
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چکیده
منابع مشابه
3-(1-Methylpyrrolidin-2-ylidene)-3H-indole sesquihydrate
The asymmetric unit of the title compound, C(13)H(14)N(2)·1.5H(2)O, contains two similar mol-ecules of 3-(1-methyl-pyrrolidin-2-yl-idene)-3H-indole, (I), and three water mol-ecules. (I) is the product of reacting indole with 1-methyl-pyrrolidin-2-one in the presence of phospho-rus oxychloride. Both organic molecules are almost completely planar; the maximum distances above and below the least-s...
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The asymmetric unit of the title compound, C(21)H(17)NO(2), contains two crystallographically independent mol-ecules of similar geometry. The indole ring systems form dihedral angles of 8.30 (5) and 9.58 (5)° with the attached phenyl rings, and 56.96 (5) and 57.68 (5)° with the aromatic rings of the respective benzyl groups. The mol-ecular conformations are stabilized by intra-molecular C-H⋯O h...
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Inclusion complexes of 2-[Arylidenamino]-1,3,4-thiadiazino[6,5b]indoles have been prepared with β-cyclodextrin so as to increase the solubility of these compounds in polar medium which may increase theirbioaccessibility. The formation of inclusion complexes is known from the study of changes in physical andspectral properties of the compounds. The stability of the inclusion complexes has been s...
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Vilsmeier-Haack reaction of 2,3,3-trimethyl-3H-benzo[g]indole, then aqueous basic work-up, leads to benzo[g]indol-2-ylidene- malondialdehydes. These react with various arylhydrazines and quinolin-2-ylhydrazine to form 3,3-dimethyl-2-(1-aryl-1H-pyrazol-4-yl)- 3H-benzo[g]indoles in good yields.
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ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1974
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.94.5_540